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臺(tái)式 ICP光譜儀組成及工作原理
The composition and working principle of desktop ICP spectrometer
ICP光譜儀是多元素順序測(cè)量的分析測(cè)試儀器。 該儀器由掃描分光器、射頻發(fā)生器、試樣引入系統(tǒng)、光電轉(zhuǎn)換、控制系統(tǒng)、數(shù)據(jù)處理系統(tǒng)、分析操作軟件組成。等離子體是在三重同心石英炬管中產(chǎn)生。炬管內(nèi)分別以切向通入氬氣，炬管上部繞有紫銅負(fù)載線圈<內(nèi)通冷卻水>當(dāng)高頻發(fā)生器產(chǎn)生的高頻電流(工作頻率40MHz功率1.2KW左右)通過線圈時(shí)，其周圍產(chǎn)生交變磁場(chǎng)，使少量氬氣電離產(chǎn)生電子和離子，在磁場(chǎng)作用下加速運(yùn)動(dòng)與其它中性原子碰撞，產(chǎn)生更多的電子和離子，在炬管內(nèi)形成渦流，在電火花作用下形成等離子炬(即等離子體)，這種等離子體溫度可達(dá)10000K以上。待測(cè)水溶液經(jīng)噴霧器形成氣溶膠進(jìn)入石英炬管中心通道。原子在受到外界能量的作用下電離，但處于激發(fā)態(tài)的原子十分不穩(wěn)定，從較高能級(jí)躍遷到基態(tài)時(shí)，將釋放出巨大能量，這種能量是以一定波長的電磁波的形式輻射出去。不同元素產(chǎn)生不同的特征光譜。這些特征光譜通過透鏡射到分光器中的光柵上，計(jì)算通過控制步進(jìn)電機(jī)轉(zhuǎn)動(dòng)光柵,傳動(dòng)機(jī)構(gòu)將分光后的待測(cè)元素特征譜線光強(qiáng)準(zhǔn)確定位于出口狹縫處，光電倍增管將該譜線光強(qiáng)轉(zhuǎn)變?yōu)殡娏鳎俳?jīng)電路處理和V/F轉(zhuǎn)換后，由計(jì)算機(jī)進(jìn)行數(shù)據(jù)處理，最后由打印機(jī)打出分析結(jié)果。
ICP spectrometer is an analytical and testing instrument for multi-element sequential measurement. The instrument consists of a scanning spectrometer, a radio frequency generator, a sample introduction system, a photoelectric conversion, a control system, a data processing system, and an analysis software. The plasma is in three concentric quartz torch produced. The torch tube respectively in the tangential direction by argon gas, the torch tube wound with copper upper load coil cooling water in < > when the high-frequency current generator generates high frequency (frequency 40MHz power 1.2KW) through the coil, the alternating magnetic field generated around, so that a small amount of argon ionized electron and ion acceleration, and other neutral atomic collisions in a magnetic field, generated more electrons and ions, forming a vortex in the torch tube, forming a plasma torch in EDM (plasma), under the action of the plasma temperature can reach more than 10000K. The measured solution by spray forming the aerosol into the quartz torch center channel. Ionization of atoms in the outside world under the action of the energy, but the atoms is very unstable, from higher level transitions to the ground state, will release enormous energy, this energy is in the form of electromagnetic radiation of a certain wavelength. Different characteristics of different elements. The spectral characteristics of shot splitter grating in the lens through the calculation, control the stepper motor rotates through the grating, the transmission mechanism will light after the measured spectral line intensity is accurately located in the exit slit, photomultiplier tube of the spectral line intensity into the current, after dealing with the circuit and V/F conversion after the data processing by computer, finally the results printed by the printer.
二、臺(tái)式 ICP光譜儀技術(shù)指標(biāo)
Two, desktop ICP spectrometer technical indicators
1.射頻發(fā)生器(RF)
1 radio frequency generator (RF)
(1) 電路類型：自激振蕩電路，全自動(dòng)點(diǎn)火，所有功能實(shí)現(xiàn)電腦軟件控制(點(diǎn)火、熄火、功率等參數(shù)設(shè)置);實(shí)時(shí)功率控制;自動(dòng)匹配調(diào)諧;光室恒溫;
(1) circuit type: self oscillation circuit, full automatic ignition, all functions to achieve the computer software control (ignition, extinction, power and other parameters); real-time power control; automatic matching tuning; room temperature;
(2) 工作頻率：40.68MHZ±0.05%
(2) operating frequency: 40.68MHZ + + 0.05%
(3) 頻率穩(wěn)定性：<0.1%
(3) frequency stability: <0.1%
(4) 輸出功率：700-1600w
(4) output power: 700-1600w
(5) 輸出功率穩(wěn)定性：≤0.3%
(5) the stability of output power is less than or equal to 0.3%:
(6) 電磁場(chǎng)泄漏輻射強(qiáng)度：距機(jī)身300mm 電場(chǎng)強(qiáng)度E:<2V/m
(6) electromagnetic radiation leakage intensity: from the fuselage 300mm electric field strength E:<2V/m
2.進(jìn)樣裝置:
2 sampling device:
(1) 輸出工作線圈內(nèi)徑25mm，3匝
(1) output coil inner diameter 25mm, 3 turns
(2) 炬管：外徑20mm的石英炬管
(2) the torch tube: Quartz torch 20mm diameter tube
(3) 同軸型噴霧器外徑6mm
(3) the diameter of coaxial sprayer 6mm
(4) 雙筒形霧室外徑35mm
(4) the outer diameter of the double drum fog chamber 35mm
(5) 氬氣流量計(jì)規(guī)格和載氣壓力表規(guī)格：
(5) specifications for argon gas flow meters and gas carrying pressure gauges:
①、 等離子體流量計(jì)(100-1000)L/h ;(1.6-16L/min)
Plasma flowmeter (100-1000) L/h; (1.6-16L/min)
②、 輔助氣流量計(jì)(6-60)L/h ;(0.1-1L/min)
Auxiliary gas flow meter (6-60) L/h; (0.1-1L/min)
③、 載氣流量計(jì)(6-60)L/h ;(0.1-1L/min)
Carrier gas flowmeter (6-60) L/h; (0.1-1L/min)
④、 載氣穩(wěn)壓閥(0-0.4MPa)
Fourth, the carrier gas regulator valve (0-0.4MPa)
儀器內(nèi)設(shè)氬氣二次穩(wěn)壓閥(0.3MPa)
The instrument is equipped with argon two pressure regulator (0.3MPa)
3.測(cè)光裝置:
3 metering device:
(1) 光電倍增管規(guī)格： R212UH
(1) photomultiplier tube specification: R212UH
(2) 光電倍增管負(fù)高壓：200-1000V ，穩(wěn)定性<0.05%
(2) photomultiplier tube negative pressure: 200-1000V, stability <0.05%
(3) 光電倍增管電流測(cè)量范圍：10-12 -10-4A
(3) photomultiplier tube current measurement range: 10-12 -10-4A
(4) 信號(hào)采集為V/F交換：1mV對(duì)應(yīng)100Hz
(4) signal acquisition for V/F exchange: 1mV corresponds to 100Hz
4.分光器:
4 light splitter:
(1) 光路: Czerny-Turner
(1) optical path: Czerny-Turner
(2) 焦距: 1000mm
(2) focal length: 1000mm
(3) 光柵規(guī)格：離子刻蝕全息光柵，刻線密度3600線/mm，
(3) specifications: ion etching grating holographic grating groove density 3600 line /mm,
刻線面積: 80×110mm，線色散率倒數(shù)：0.26nm
Line area: 80 x 110mm, reciprocal dispersion line: 0.26nm
(4) 波長范圍：190-500nm
(4) wavelength range: 190-500nm
(5) 分辨率: ≤0.008nm
(5) resolution: 0.008nm
(6) 掃描波長范圍3600線/mm 掃描波長范圍：190-500nm
(6) scanning wavelength range of 3600 lines /mm scanning wavelength range: 190-500nm
(7) 步進(jìn)電機(jī)驅(qū)動(dòng)最小步距：0.0006nm
(7) stepper motor drive minimum step: 0.0006nm
(8) 入射狹縫：20μm 出射狹縫：25μm
(8): 20 m entrance slit and exit slit: 25 m
(9) 發(fā)射鏡規(guī)格：(78 × 105 × 16)mm
(9) specification of transmitting mirror: (78 x 105 x 16) mm
(10) 透鏡ф30，1：1成像
(10) Phi 30 1:1 imaging lens.
?5.應(yīng)用行業(yè)分類
5 Application Industry Segmentation
1、金屬類
1, metal
鋼鐵：包括碳素鋼、鑄鐵、合金鋼、高純鐵、鐵合金、硅鐵、錳鐵、釩 鐵、 鐵礦石，鉛的冶煉等。
Steel: steel, cast iron, alloy steel, Gao Chuntie, iron alloy, ferrosilicon, ferromanganese, vanadium iron, iron ore, lead smelting.
2、有色金屬分析：
2, non-ferrous metal analysis:
純銅，純鋁和合金中的雜質(zhì)元素分析。
Pure copper, pure aluminum alloy and analysis of impurity elements in.
貴金屬的純度分析：Au、Ag、Pt、Pd、Ir、Rh、Os、Ru。
Analysis of the purity of precious metals: Au, Ag, Pt, Pd, Ir, Rh, Os, Ru.
3、環(huán)境檢測(cè)類
3, environmental testing
水質(zhì)分析：礦泉水、自來水、河水、海水、污水、廢水等。
Water quality analysis: mineral water, tap water, river water, sea water, sewage, waste water, etc..
食品分析：包括食品、飲料等。
Food analysis: including food, beverages, etc..
土壤成份分析：生物和植物樣品的分析。
Analysis of soil composition: analysis of biological and plant samples.
4、稀土材料和稀土永磁類
4, rare earth materials and rare earth permanent magnet
稀土元素全分離，此儀器高分辨率非常適合稀土元素的分析。
The separation of rare earth elements is very suitable for the analysis of rare earth elements.
稀土永磁材料中對(duì)釹鐵硼材料的配分和成份的分析。
Analysis of the distribution and composition of NdFeB materials in rare earth permanent magnetic materials.
5、地質(zhì)礦物的分析
5, geological mineral analysis
精選礦的分析、普查找礦分析
Analysis of mineral exploration and prospecting of ore selection
6、食品醫(yī)藥分析
6, food and pharmaceutical analysis
食品中有益、有害元素的分析、藥材中的微量元素分析
Analysis of beneficial and harmful elements in food and trace elements in medicinal materials
三、臺(tái)式 ICP光譜儀整機(jī)技術(shù)指標(biāo)
Three, desktop ICP spectrometer technical indicators
測(cè)量波長范圍：
Measuring wavelength range:
180-500nm 3600L/mm光柵
180-500nm 3600L/mm grating
180-800nm 2400 L/mm光柵
180-800nm 2400 L/mm grating
2.測(cè)量精度(重復(fù)性)：平均相對(duì)標(biāo)準(zhǔn)偏差RSD≤1%
2 measurement precision (repeatability): the average relative standard deviation is less than 1% RSD
3.測(cè)量穩(wěn)定性：平均相對(duì)標(biāo)準(zhǔn)偏差RSD≤2
3 measuring stability: the average relative standard deviation is less than 2 RSD
4.檢出下限：亞PPb級(jí)
4 detection limit: sub PPb level
四、安裝條件
Four, installation conditions
1、儀器正常工作條件：實(shí)驗(yàn)室內(nèi)清潔、干燥、無灰塵、無振動(dòng)。室溫保持 為22℃±3℃
1, the normal working conditions of the instrument: clean, dry, no dust, no vibration in the laboratory. Room temperature maintained at 22 degrees C + + 3
2、房間：15平米左右為宜，配有標(biāo)準(zhǔn)溶液試劑柜，電腦桌、電腦椅，空調(diào)1.5 —2匹。
2, room: about 15 square meters is appropriate, with standard solution reagent cabinet, computer desk, computer chair, air conditioning 1.5 - 2.
3、電源：220V，22A，使用4平方的電線。
3, power supply: 220V, 22A, the use of 4 square wire.
4、接地：為了安全和儀器的穩(wěn)定，必須有高頻接地，用300×300×3mm的紫銅 板埋于地下1.5米深處，用寬30×0.5mm的紫銅帶接到主機(jī)的機(jī)殼上。
4, ground: for safety and stability of the instrument, there must be a high frequency ground, with 300 x 300 x 3mm copper plate buried 1.5 meters underground, a width of 30 * 0.5mm to a host of the copper belt.
5、排風(fēng)：要求在主機(jī)上方安裝排風(fēng)筒，外接煙囪并用排風(fēng)扇將ICP燃燒后的廢 氣排到室外。
5, exhaust requirements in the host is installed above the exhaust tube, external chimney and exhaust fan for the exhaust gas after combustion to discharge ICP.
6、氬氣：可使用普通氬氣99.99%即可
6, argon: ordinary argon can be used 99.99%
五、保修：
Five, warranty:
北京中曄儀元科技有限公司將提供12個(gè)月的保修期, 自簽字驗(yàn)收之日起計(jì) 算，但不超過發(fā)貨之日起15個(gè)月. 在保修期期內(nèi)，北京中曄儀元科技有限公 司免費(fèi)維修，由于非甲方人為因素造成儀器故障及損壞，即由乙方免費(fèi)負(fù)責(zé) 解決(消耗品除外);
Beijing ye ie-tech Co. Ltd will provide the warranty period of 12 months, counting from the date of signing the acceptance, but not more than 15 months from the date of delivery. In the warranty period, Beijing ie-tech Co. Ltd. Ye free maintenance, equipment failure and damage caused by the non party human factors. Party B is responsible for solving free (except consumables);
六、臺(tái)式 ICP光譜儀售后服務(wù)：
Six, desktop ICP spectrometer after-sales service:
在收到用戶的要求維修書面通知的3小時(shí)內(nèi)，北京中曄儀元科技有限公司 的技術(shù)人員做出響應(yīng)如果需要趕赴用戶工作現(xiàn)場(chǎng)，技術(shù)人員將在收到 書面通知的2個(gè)工作日內(nèi)到達(dá)用戶工作地。
After receiving the written notice of the maintenance requirements of users within 3 hours, if you need to respond to user work on-site technical staff in Beijing ye ie-tech Co. Ltd., technical staff will work to reach users within 2 working days of receipt of the written notice within the.
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